Effect of Microstructures of Carbon Nanoproducts Grown on Carbon Fibers on the Interfacial Properties of Epoxy Composites.

Two kinds of carbon nanoproducts with different microstructures, namely, carbon nanotubes (CNTs) and carbon nanofibers (CNFs), were grown on the surface of carbon fibers (CFs) by chemical vapor deposition (CVD) at low temperatures to improve the interface bonding between fibers and resins. The short-beam method and the micro-debonding method were used to test the interlaminar shear strength (ILSS) and interfacial shear strength (IFSS) of the composites. The results showed that the contribution of CNTs to the improvement of interfacial properties was better than that of CNFs. Specifically, the ILSS and IFSS of the CF-CNFs/epoxy composites increased by 18.59 and 24.39%, respectively, while the ILSS and IFSS of the CF-CNTs/epoxy composites increased by 26.97 and 47.79%, respectively. Compared with CNFs, the high degree of graphitization of CNTs and the π-interactions with the resin can better induce the formation of an interphase between the fiber and the resin, which suppressed the initiation of cracks and extended the propagation path of the cracks in the composites.

Influencing factors and growth kinetics analysis of carbon nanotube growth on the surface of continuous fibers.

Carbon nanotubes (CNTs) were continuously grown on the surface of the moving carbon fiber by chemical vapor deposition method using a custom-designed production line to prepare composite reinforcements on a large-scale. The systematic study of different parameters affecting the CNT growth revealed simple growth kinetics, which helps to control the surface morphology and structural quality of CNTs. Since hydrogen maintains the activity of the catalyst, it promotes the growth of CNTs in a continuous process. The increase of acetylene partial pressure promotes the accumulation of amorphous or graphite carbon on the catalyst surface, resulting in the decrease of CNT growth rate when acetylene concentration reaches 40%. The growth temperature significantly affects the CNT diameter and structural quality. As the temperature increases, the crystallinity of the tube wall increases obviously, and the CNT diameter increases due to the aggregate growth of the catalyst particles. According to the Arrhenius formula, the apparent activation energy is observed to be 0.67 eV, which proves that both bulk diffusion and surface diffusion exist when activated carbon passes through the catalyst to form CNTs.

Millisecond tension-annealing for enhancing carbon nanotube fibers.

Mechanically strong carbon nanotube (CNT) fibers have increasingly become the focus of the present research in the fiber industry. However, the weak or even a lack of interconnections between adjacent CNTs induces much inter-tube slippages during fiber failure, and thus results in their low mechanical strength. Moreover, achieving fast cross-linking between neighbouring CNTs on a large scale to prevent the failure by slip is still a big challenge. Herein we report an ultrafast and continuous tension-annealing process to achieve the considerably improved tube alignment and strong covalent cross-linking of neighbouring CNTs in milliseconds, resulting in great improvement of the fiber performance. The CNT fibers were heated to high temperature (∼2450 °C) by Joule heating under the applied tension and subsequently annealed for just 12 ms. Due to the rapid electromechanical response of the fibers, instant nanotube rearrangements coupled by the formation of cross-links robustly bonding the adjacent CNTs occurred at power-on, which could be attributed to the considerable increases of strength and modulus by factors of 2.9 (up to 3.2 GPa) and 4.8 (up to 123 GPa), respectively. The resultant fibers showed high specific strength (2.2 N per tex), comparable with that of PAN-based carbon fibers, and high specific electrical conductivity higher than that of PAN-based carbon fibers. Moreover, the obtained strongly crosslinked and highly dense structures also endowed the fibers with the significantly improved thermal stability under a high-temperature oxidation atmosphere. Moreover, a continuous tension-annealing process was designed to achieve the large scale production of high performance fibers with the average strength of 2.2 GPa. The high-toughness, lightweight and continuous features together with their outstanding mechanical and electrical properties would certainly boost the large-scale applications of CNT fibers.

Direct intramolecular double cross-dehydrogentive-coupling (CDC) cyclization of N-(2-pyridyl)amidines under metal-free conditions.

A facile transition-metal-free protocol to form 2-iminoimidazo[1, 2-a]-pyridines bearing a -CHBr2 group and an aza-quaternary carbon center at the 3 position from N-(2-pyridyl)amidines substrates, in which the new heterocyclic skeletons constructed from amidines via radical reactions or nucleophilic substitution reactions are promoted only by CBr4 under mild conditions, is demonstrated. The reactions were realized by intramolecular CDC reaction involving C-N and C-C bond formation via the sequential C(sp3)-H bifunctionalization mode on the same carbon atom under mild conditions. Moreover, this work also provides an excellent and representative example for CBr4 as an efficient reagent to initiate radical reactions under initiator-free conditions or to give rise to nucleophilic substitution reactions only by base.

Synthesis and growth mechanism of carbon nanotubes growing on carbon fiber surfaces with improved tensile strength.

An effective approach has been developed for the catalytic decomposition of acetylene (C2H2) by chemical vapor deposition (CVD), to achieve homogeneous growth of carbon nanotubes (CNTs) on the surfaces of carbon fibers. The morphology of CNTs grown on carbon fiber surfaces was observed by a scanning electron microscope and high-resolution transmission electron microscope, which revealed the uniform coverage of CNTs on the carbon fiber surfaces. The single fiber tensile test demonstrated that the tensile strength of carbon fibers could be increased by more than 12% with the catalytic growth of CNTs on their surface. The reparation of the damage caused during the formation of catalyst nanoparticles, and the cross-link of neighboring graphite crystallites induced by CNTs all occurred during the CVD process, which were considered to be the main reasons for improvement. The growth mechanism model of CNTs formation was established based on the thermodynamics principle and the interface microstructure of CNT-grown carbon fiber, illuminating the detailed mechanism for the growth of CNTs and the change of the shape of catalyst particles.